个人经历
教育经历
2011-2013 美国能源部阿贡国家实验室材料科学部 博士后;
2007-2011 美国南卡罗来那大学 博士 无机化学;
工作经历
2015-今 华东师范大学 紫江青年学者 研究员;
2014-2015 中国科学院上海硅酸盐研究所 所百人计划。
研究方向
研究方向为新型功能材料,具体包括以下三个方面:
1. 氧化物功能材料: 利用助溶剂晶体生长等方法,制备氧化物磁性材料与多铁材料单晶,并研究其磁性、输运和极化性等。另外,通过固相合成以及液相合成等方法,合成氧化物荧光材料,特别是具有高能量转换效率、低原料成本及高稳定性的单相白色发光材料。
2. 荧光及电化学传感器: 利用纳米粒子的荧光发射和光吸收性能,构建新型荧光传感器。利用电化学方法,构建电化学传感器。通过荧光及电化学传感器等方法,灵敏探测人体代谢的关键产物和药物,为快速疾病诊断提供依据。
3. 选择性吸附与分离材料:合成新型吸附材料,用于被分析物的富集和纯化。结合色谱-质谱联用等手段,精确测定在法医、毒理、药物和食品等领域具有重要意义的化合物。
主讲课程
电子材料制备与晶体生长(研究生课程)。
学术成果
科研项目
国家自然科学基金青年项目,中国科学院所百人启动经费,华东师范大学紫江青年学者启动经费等。
期刊论文
在Journal of the American Chemical Society, Science, Chemical Engeering Journal, Biosensors and Bioelectronics, Physics Review Materials, ACS Sustainable Chemistry & Engineering, Inorganic Chemistry, Sensors & Actuators B等学术期刊发表论文60余篇,其中以第一作者或通讯作者发表30余篇。被引用1100多次,H index为14.
[63] T Liu, S Zhang, W Liu, S Zhao, Z Lu, Y Wang, G Wang, P Zou, X Wang,
Q Zhao*,H Rao*, Smartphone based platform for ratiometric fluorometric and colorimetric determination H2O2 and glucose, Sensors and Actuators B Chemical 2020, 305, 127524
[62] Z Lu, Y Li, T Liu, G Wang, M Sun, Y Jiang, H He, Y Wang, P Zou, X Wang,Q Zhao*, H Rao,* A dual-template imprinted polymer electrochemical sensor based on AuNPs and nitrogen-doped graphene oxide quantum dots coated on NiS2/biomass carbon for simultaneous determination of dopamine and chlorpromazine, Chemical Engineering Journal 2020, 389, 124417
[61]Q Lu, H Guo, Y Zhang, X Tang, W Lei, R Qi, J Chu, D Li*, Q Zhao*Graphene oxide-Fe3O4 nanocomposite magnetic solid phase extraction followed by UHPLC-MS/MS for highly sensitive determination of eight psychoactive drugs in urine samples,Talanta, 2020, 120212
[60] Y Yao, J Zhong, Z Lu, X Liu, Y Wang, T Liu, P Zou, X Dai, X Wang, F Ding,Q Zhao*, H Rao* Nitrogen-doped carbon frameworks decorated with palladium nanoparticles for simultaneous electrochemical voltammetric determination of uric acid and dopamine in the presence of ascorbic acid, Microchimica Acta, 2019, 186, 795
[59]S Yang, Y Dai, Y Shen, C Duan, Q Rao, H Peng, F Yang, Y Shan*, Q Zhao*Blue emission from Sr0. 98Ga2B2O7: 0.01 Bi3+, 0.01 Dy3+ phosphor with high quantum yield, Journal of Alloys and Compounds, 2019, 151849
[58]Rui Chen, Ze Ning, Chao Zheng, Yongsheng Yang, Chengyu Zhang, Xuemei Ou, Kehong Chen, Hongyan Yu, Xiaojuan Wei,Q Zhao*Jianguo He*Simultaneous determination of 16 alkaloids in blood by ultra high-performance liquid chromatography-tandem mass spectrometry coupled with supported liquid extraction, J Chromatogr. B 2019 121789
[57] W Liu, F Ding, Y Wang, Z Lu, P Zou, X Wang, Q Zhao,* H Rao,*A dual‐readout nanosensor based on biomass‐based C‐dotsand chitosan@AuNPs with hyaluronic acid for determination ofhyaluronidase Luminescence, 2019, 1-9
[56]X Peng, Y Wan, Y Wang, T Liu, P Zou, X Wang,Q Zhao, F Ding, H Rao,Flower‐like Ni (II)‐based Metal‐organic Framework‐decorated Ag Nanoparticles: Fabrication, Characterization and Electrochemical Detection of Glucose,Electroanalysis 2019
[55] X Peng, X Chen, T Liu, C Lu, M Sun, F Ding, Y Wang, P Zou, X Wang,Q Zhao,*H Rao*,
Rose‐like Nanocomposite of Fe‐Ni Phosphides/Iron Oxide as Efficient Catalyst for Oxygen Evolution Reaction, Chemistry-An Asian Journal, 2019
[54] Y Wang, L Yao, X Liu, J Cheng, W Liu, T Liu, M Sun, L Zhao, F Ding, Z Lu, P Zou, X Wang,Q Zhao,*H Rao*,CuCo2O4/N-Doped CNTs loaded with molecularly imprinted polymer for electrochemical sensor: Preparation, characterization and detection of metronidazole, Biosensors and Bioelectronics, 2019, 142, 111483
[53]QZhao,J.-H. Sim, Z. Zhang, H. Su, F. Han, Q. Zhang, B. Tian, Q. Xu, M.-J. Han, C.-G. Duan, and J. F. Mitchell,Tetrahedral coordination and low-spin configuration in a 5d oxide, Physics Review Materials, 2019, 3, 063607
[52]Y Shen, J Cai, H Ding, X Shen, Y Fang, W Tong, X Wan,Q Zhao,C Duan.
Role of Lone‐Pairs in Driving Ferroelectricity of Perovskite Oxides: An Orbital Selective External Potential StudyAdvanced Theory and Simulations 2019, 2, 1900029
[51] Q Lu, L Liu, X Zhang, Y Cheng, Y Huang, Y Shan,Q Zhao,G Zhang, D Li,
Graphene transparent conductive films directly grown on quartz substrates by assisted catalysis of Cu nanoparticles, 2019 J Material Science, 54 10312-10324
[50]Z Zhou, W Liu, Y Wang, F Ding, X Liu,Q Zhao,*P Zou, X Wang, H Rao*,
A fluorometric and colorimetric method for determination of trypsin by exploiting the gold nanocluster induced aggregation of hemoglobin-coated gold nanoparticlesMicrochimica Acta 2019 (186) 272
[49] G Yue, S Li, W Liu, F Ding, P Zou, X Wang,Q Zhao,H. Rao,Ratiometric fluorescence based on silver clusters and N, Fe doped carbon dots for determination of H2O2and UA: N, Fe doped carbon dots as mimetic peroxidase,Sensors Actuators B Chem. (287) 2019 408-415
[48] J Wang, R Du, W Liu, L Yao, F Ding, P Wang, X Wang,Q Zhao,*H Rao,*
Colorimetric and fluorometric dual-signal determination of dopamine by the use of Cu-Mn-O microcrystals and C-dots Sensors Actuators B Chem. (290) 2019 125-132
[47]Y Wang, Y Yang, W Liu, F Ding, P Zou, X Wang,Q Zhao*, H Rao*,A carbon dot-based ratiometric fluorometric and colorimetric method for determination of ascorbic acid and of the activity of ascorbic acid oxidase,Microchimica Acta 186 (4), 246 2019
[46] H Guo, Y Gao, D Guo, W Liu, J Wang, J Zheng, J Zhong,Q Zhao*,Sensitive, rapid and non-derivatized determination of glyphosate, glufosinate, bialaphos and metabolites in surface water by LC–MS/MS, SN Applied Sciences 1 (4), 305 2019
[45] G Yue, S Li, W Liu, F Ding, P Zou, X Wang,Q Zhao,H Rao,Ratiometric fluorescence based on silver clusters and N, Fe doped carbon dots for determination of H2O2 and UA: N, Fe doped carbon dots as mimetic peroxidase,Sensors and Actuators B: Chemical 2019
[44]Y Dai, S Yang, Y Shan, CG Duan, H Peng, F Yang*,Q Zhao*,Single-Composition White Light Emission from Dy3+ Doped Sr2CaWO6,Materials 2019, 12 (3), 431
[43]X. Gao, Y. Sun, H. You, Y. Dai, H. Guo,Q. Zhao*,
Simultaneousdetermination of amitraz, chlordimeform, formetanate and metabolites in humanblood by liquid chromatography tandem mass spectrometry with phospholipidremoval pretreatment Biomed. Chroma. DOI:10.1002/bmc.4477
[42]B. Tian, L. Liu, M. Yan, J. Wang,Q. Zhao, N. Zhong, P. Xiang, L. Sun, H. Peng, H. Shen, T. Lin, B. Dkhil, Xi. Meng, J. Chu, X. Tang, C. Duan,A Robust Artificial Synapse Based on Organic Ferroelectric Polymer, Adv. Elec. Mater. 5 (2019) 1800600 doi.org/10.1002/aelm.201800600
[41]Y. Wang, X. Zhu, F. Ding, Y. Liu, L. Yang, P. Zou,Q. Zhao, X. Wang, H. RaoColorimetric detection of gallic acid based on the enhanced oxidase‐like activity of floral‐like magnetic Fe3O4@MnO2, Luminescence, 34 (2019) 55-63 DOI:10.1002/bio.3576
[40] Y. Wang, J. Cheng, X. Liu, F. Ding, P. Zou, X. Wang,Q. Zhao,* H. Rao*C3N4 nanosheets/Metal-organic framework wrappedwith molecularly imprinted polymer sensor: Fabrication, characterization and electrochemical detection of furosemideACS Sustain Chem & Eng 6 (2018) 16847-16858 DOI:10.1021/acssuschemeng.8b04179
[39] L. Yang, Y. Liu,Q. Zhao, F. Ding, Y. Wang, P. Zou, X. Wang, H. Rao,Colorimetric determination of dopamine by exploiting the enhanced oxidase mimicking activity of hierarchical NiCo2S4-rGO composites
Microchim. Acta 185 (2018)496 10.1007/s00604-018-3035-8
[38]X. Gao, H. Li, H. Li, S. Dong, J. Chu, H. Guo,Q. Zhao,*Sensitive determination of nine anticoagulant rodenticides in blood by high resolution mass spectrometry with supported liquid extraction pretreatment,Forensic Sci. Int. 292 283 39-44 (2018)10.1016/j.forsciint.2018.09.009
[37]Y. Wang, L. Mao, W. Liu, F. Ding, P. Zou, X. Wang,Q. Zhao,* H. Rao,*A ratiometric fluorometric and colorimetric probe for the β-thalassemia drug deferiprone based on the use of gold nanoclusters and carbondots, Microchim. Acta 185 (2018) 442 DOI: doi.org/10.1007/s00604-018-2982-4
[36] Y. Wang, Z. Zhang, X. Liu, F. Ding, P. Zou, X. Wang,Q. Zhao,*H. Rao,* MOF-derivedNiO/NiCo2O4andNiO/NiCo2O4rGOas highly efficientand stable electrocatalystsfor oxygen evolution reaction, ACS Sustain Chem & Eng. 6 (2018) 12511-12521DOI:10.1021/acssuschemeng.8b03221
[35]Y. Wang, R. Liang, W. Liu,Q. Zhao, X. Zhu, L. Yang, P. Zou, X. Wang, F. Ding, H. Rao,A dual-mode probe for colorimetric and fluorometric detection of cysteine based on phosphorus/nitrogen co-doped CQDs and gold nanorods,Sensors Actuators B Chem. 273 (2018) 1627-1634doi.org/10.1016/j.snb.2018.07.084.
[34] W. Liu, F. Ding, Y. Wang, L. Mao, R. Liang, P. Zou, X. Wang,Q. Zhao,*H. Rao,* Fluorometric and colorimetric sensor array for discrimination of glucose using enzymatic-triggered dual-signal system consisting of Au@Ag nanoparticles and carbon nanodots, Sensors Actuators B Chem. 265 (2018) 310–317. doi:10.1016/J.SNB.2018.03.060.
[33] Y. Wang, Y. Yang, W. Liu, F. Ding,Q. Zhao,*P. Zou, X. Wang, H. Rao,* Colorimetric and fluorometric determination of uric acid based on the use of nitrogen-doped carbon quantum dots and silver triangular nanoprisms, Microchim. Acta. 185 (2018) 281. doi:10.1007/s00604-018-2814-6.
[32] H. Guo, J. Wang, Y. Wu, W. Liu, J. Bu,Q. Zhao,*Sensitive and simultaneous determination of nine anticoagulant rodenticides in human blood by UPLC–MS-MS with phospholipid removal pretreatment, J. Anal. Toxicol. (2018). doi:10.1093/jat/bky024.
[31] Y. Wu, H. Guo, J. Bu, Y. Tan, J. Zhong,Q. Zhao,*Rapid and sensitive determination of formamidines and metabolites with HPLC-MS/MS using core-shell columns, J. Chromatogr. B. 1076 (2018) 22–28. doi:10.1016/j.jchromb.2018.01.012.
[30] H. Guo, H. Wang, J. Zheng, W. Liu, J. Zhong,Q. Zhao,*Sensitive and rapid determination of glyphosate, glufosinate, bialaphos and metabolites by UPLC–MS/MS using a modified Quick Polar Pesticides Extraction method, Forensic Sci. Int. 283 (2018) 111–117. doi:10.1016/J.FORSCIINT.2017.12.016.
[29] X. Gao, H. Guo, J. Wang,Q. Zhao,*Sensitive and rapid determination of pyrethroids in human blood by gas chromatography-tandem mass spectrometry with ultrasound-assisted dispersive liquid-liquid microextraction, Drug Test. Anal. (2018). doi:10.1002/dta.2358.
[28] Z. Yan, H. Li, H. Li, G. Lai, J. Chu, H. Guo,Q. Zhao,*Simultaneous determination of nine anticoagulant rodenticides by ultra- performance liquid chromatography – tandem mass spectrometry with ultrasound-assisted low – density solvent dispersive liquid – liquid microextraction, J. Chromatogr. B. 1092 (2018) 453–458. doi:10.1016/j.jchromb.2018.06.053.
[27] Y. Wang, Y. Liu, F. Ding, X. Zhu, L. Yang, P. Zou, H. Rao,Q. Zhao, X. Wang, Colorimetric determination of glutathione in human serum and cell lines by exploiting the peroxidase-like activity of CuS-polydopamine-Au composite, Anal. Bioanal. Chem. (2018) 1–9. doi:10.1007/s00216-018-1117-4.
[26] H. Rao, X. Liu, F. Ding, Y. Wan, X. Zhao, R. Liang, P. Zou, Y. Wang, X. Wang,Q. Zhao, Nitrogen-doped carbon nanosheet frameworks decorated with Fe and molecularly imprinted polymer for simultaneous detection of mebendazole and catechol, Chem. Eng. J. 338 (2018) 478–487. doi:10.1016/J.CEJ.2018.01.064.
[25] Y. Wang, J. Zhong, F. Ding,Q. Zhao, Z. Zhang, X. Liu, Y. Liu, H. Rao, P. Zou, X. Wang, A bifunctional NiCo2S4/reduced graphene oxide@polyaniline nanocomposite as a highly-efficient electrode for glucose and rutin detection, New J. Chem. 42 (2018) 9398–9409. doi:10.1039/C8NJ00663F.
[24] Y. Gim, A. Sethi,Q. Zhao,J.F. Mitchell, G. Cao, S.L. Cooper, Isotropic and anisotropic regimes of the field-dependent spin dynamics in Sr2IrO4: Raman scattering studies, Phys. Rev. B. 93 (2016). doi:10.1103/PhysRevB.93.024405.
[23] F. Han, X. Wan, D. Phelan, C.C. Stoumpos, M. Sturza, C.D. Malliakas, Q. Li, T.-H. Han,Q. Zhao, D.Y. Chung, M.G. Kanatzidis, Antiferromagnetic Kondo lattice in the layered compoundCePd1 − xBi2and comparison to the superconductorLaPd1 − xBi2, Phys. Rev. B. 92 (2015) 045112.doi:10.1103/PhysRevB.92.045112.
[22]Q. Zhao, F. Han, C.C. Stoumpos, T.-H. Han, H. Li, J.F. Mitchell, New Insulating Antiferromagnetic Quaternary Iridates MLa10Ir4O24 (M = Sr, Ba), Sci. Rep. 5 (2015) 11705. doi:10.1038/srep11705.
[21] Q. Ji, Y. Ma, K. Hu, B. Gao, G. Mu, W. Li, T. Hu, G. Zhang,Q. Zhao, H. Zhang, F. Huang, X. Xie, Synthesis, Structural, and Transport Properties of Cr-Doped BaTi2As2O, Inorg. Chem. 53 (2014) 13089–13092. doi:10.1021/ic502192h.
[20] Y.K. Kim, O. Krupin, J.D. Denlinger, A. Bostwick, E. Rotenberg,Q. Zhao, J.F. Mitchell, J.W. Allen, B.J. Kim, Fermi arcs in a doped pseudospin-1/2 Heisenberg antiferromagnet, Science (80-. ). 345 (2014). doi:10.1126/science.1251151.
[19] C.A. Stackhouse, D.E. Bugaris, H.S. Khalsa,Q. Zhao, M. Bharathy, H.-C. Zur Loye, Syntheses and crystal structures of the compounds NaLnTiO4 (Ln = La, Pr, Nd), J. Chem. Crystallogr. 42 (2012). doi:10.1007/s10870-012-0273-1.
[18] H.-C. zur Loye,Q. Zhao, D.E. Bugaris, W.M. Chance, 2H-perovskite related oxides: Synthesis, structures, and predictions, CrystEngComm. 14 (2012) 23.
[17]Q. Zhao, J. Darriet, M.H. Whangbo, L. Ye, C. Stackhouse, H.C. Zur Loye, Intriguing interconnections among phase transition, magnetic moment, and valence disproportionation in 2H-perovskite related oxides, J. Am. Chem. Soc. 133 (2011) 20981–20994.
[16]Q. Zhao, S. Nellutla, W.J. Son, S.A. Vaughn, L.F. Ye, M.D. Smith, V. Caignaert, M. Lufaso, T.M. Pekarek, A.I. Smirnov, M.H. Whangbo, H.C. zur Loye, Ba4KFe3O9: A Novel ferrite containing discrete 6-membered rings of corner-sharing FeO4 tetrahedra, Inorg. Chem. 50 (2011) 10310–10318. doi:Doi 10.1021/Ic201374g.
[15]Q. Zhao, M.D. Smith, H.-C. Zur Loye, Crystal growth and structure determination of the mixed-valent iron (III/IV) oxides Sr2-x LnxFeO4 (Ln = Nd, Sm, Eu), J. Chem. Crystallogr. 41 (2011). doi:10.1007/s10870-010-9950-0.
[14]Q. Zhao, D.E. Bugaris, C.A. Stackhouse, M.D. Smith, H.-C. zur Loye, Crystal growth and structure determinations of potassium hafnates: K2Hf2O5 and K4Hf5O12, Mater. Res. Bull. 46 (2011) 166–169. doi:10.1016/j.materresbull.2010.11.025.
[13] M. Bharathy,Q. Zhao, H.-C. Zur Loye, Crystal growth of KInO2 from a hydroxide flux, J. Cryst. Growth. 312 (2010). doi:10.1016/j.jcrysgro.2010.08.039.
[12] H.-C. zur Loye, T.J. Hansen,Q. Zhao, S.J. Mugavero III, R.L. Withers, M.D. Smith, Crystal growth of novel lanthanide-containing platinates K4[Ln6Pt2O15] (Ln = La, Pr, Nd, Sm) with a unique framework structure, Inorg. Chem. 48 (2009). doi:10.1021/ic801789e.
[11] X. Ni,Q. Zhao, D. Zhang, X. Zhang, H. Zheng, Novel hierarchical nanostructures of nickel: Self-assembly of hexagonal nanoplatelets, J. Phys. Chem. C. 111 (2007) 601–605.
[10] X. Ni,Q. Zhao, Y. Zhang, H. Zheng, Reticular nickel microwires with assembled nanostructures: Synthesis, magnetism and catalysis for the growth of carbon nanotubes, Eur. J. Inorg. Chem. (2007) 422–428.
[9] X. Ni,Q. Zhao, Y. Zhang, J. Song, H. Zheng, K. Yang, Large scale synthesis and electrochemical characterization of hierarchical β-Ni(OH)2 flowers, Solid State Sci. 8 (2006). doi:10.1016/j.solidstatesciences.2006.05.005.
[8] X. Ni,Q. Zhao, F. Zhou, H. Zheng, J. Cheng, B. Li, Synthesis and characterization of NiO strips from a single source, J. Cryst. Growth. 289 (2006). doi:10.1016/j.jcrysgro.2005.10.017.
[7] G. Xi, K. Xiong,Q. Zhao, R. Zhang, H. Zhang, Y. Qian, Nucleation-dissolution-recrystallization: A new growth mechanism for t-selenium nanotubes, Cryst. Growth Des. 6 (2006). doi:10.1021/cg050444c.
[6] X. Ni,Q. Zhao, B. Li, J. Cheng, H. Zheng, Interconnectedβ-Ni(OH)2 sheets and their morphology-retained transformation into mesostructured Ni, Solid State Commun. 137 (2006) 585–588.
[5] X. Ni,Q. Zhao, H. Zheng, J. Song, D. Zhang, X. Zhang, A novel chemical reduction route towards the synthesis of crystalline nickel nanoflowers from a mixed source, Eur. J. Inorg. Chem. (2005). doi:10.1002/ejic.200500453.
[4] X. Ni,Q. Zhao, J. Cheng, H. Zheng, B. Li, D. Zhang, High-yield synthesis of nickel flowers from nickel hydroxide precursor, Chem. Lett. 34 (2005). doi:10.1246/cl.2005.1408.
[3] X. Ni,Q. Zhao, D. Zhang, D. Yang, H. Zheng, Large scaled synthesis of chainlike nickel wires assisted by ligands, J. Cryst. Growth. 280 (2005). doi:10.1016/j.jcrysgro.2005.03.053.
[2] X. Ni, X. Su, H. Zheng, D. Zhang, D. Yang,Q. Zhao, Studies on the one-step preparation of iron nanoparticles in solution, J. Cryst. Growth. (2005). doi:10.1016/j.jcrysgro.2004.12.009.
[1] X. Ni, L. Chen, H. Zheng, D. Zhang,Q. Zhao, J. Song, Synthesis of nickel nanocrystallites with hexagonal flake-like morphology from nickel dimethylglyoximate, Chem. Lett. 33 (2004). doi:10.1246/cl.2004.1564.