男,1980年生,湖北省赤壁市人,博士,中国有机化学家,中山大学教授、博士生导师。
人物经历
教育经历
1998-2002年,湖北大学,本科,
应用化学专业。
2002-2007年,
中国科学院大连化学物理研究所攻读博士学位,有机化学专业,导师:余正坤研究员。研究生期间,第一年在
中国科学技术大学学习基础课程;2005年,作为交换学生在加拿大University of Ottawa的Howard Alper教授组学习和从事研究一年。
2008-2010年,在加拿大University of Toronto从事博士后研究,导师:Vy M. Dong教授。
2010-2013年,在美国Colorado State University从事博士后研究,导师: Tomislav Rovis教授。
工作经历
2013年6月,
中山大学化学学院,教授、博士生导师。
科研方向
不对称催化与合成,有机硒、硫小分子催化,
有机氟化学。
获奖情况
宝钢优秀学生奖学金 2008年
学术成果
1.Zhao, X.; Glover, G. S.; Oberg, K. M.; Dalton, D. M.; Rovis, T.* SNAr-Derived Decomposition By-products Involving Pentafluorophenyl Triazolium Carbenes.Synlett2013,24, 1229-1232.
2.Zhao, X.; Ruhl, K. E.; Rovis, T.* N-Heterocyclic Carbene-Catalyzed Asymmetric Oxidative Hetero-Diels-Alder Reactions with Simple Aliphatic Aldehydes.Angew. Chem. Int. Ed.2012,51, 12330-12333.
3.Zhao, X.; DiRocco, D. A.; Rovis, T.* N-Heterocyclic Carbene and Brønsted Acid Cooperative Catalysis: Asymmetric Synthesis of trans-γ-Lactams.J. Am. Chem. Soc.2011,133, 12466-12469.
4.Zhao, X.; Dong, V. M.* Reductive Elimination from Pd(IV) Sulfinate Complexes.Angew. Chem. Int. Ed.2011,50, 932-934.
5.Zhao, X.; Yeung, C. S.; Dong, V. M.* Palladium-Catalyzed ortho-Arylation of O-Phenylcarbamates with Simple Arenes and Sodium Persulfate.J. Am. Chem. Soc.2010,132, 5837-5844.
6.Zhao, X.; Dimitrijević, E.; Dong, V. M.* Palladium-Catalyzed C–H Bond Functionalization with Arylsulfonyl Chlorides.J. Am. Chem. Soc.2009,131, 3466-3467.
7.Zhao, X.; Yu, Z.* Rhodium-Catalyzed Regioselective C–H Functionalization via Decarbonylation of Acid Chlorides and C–H Bond Activation under Phosphine-Free Conditions.J. Am. Chem. Soc.2008,130, 8136-8137.
8.Zhao, X.; Yu, Z.;* Xu, T.; Wu, P.; Yu, H. Novel Brønsted Acid-Catalyzed Three-Component Alkylation of Indoles with N-Phenylselenophthalimide and Styrenes.Org. Lett.2007,9, 5263-5266.
9.Zhao, X.; Alper, H.;* Yu, Z.* Stereoselective Hydroxycarbonylation of Vinyl Bromides to the Corresponding α,β-Unsaturated Carboxylic Acids in the Ionic Liquid [BMIM]PF6.J. Org. Chem.2006,71, 3988-3990.
10.Zhao, X.; Yu, Z.;* Yan, S.; Wu, S.; Liu, R.; He, W.; Wang, L. Ruthenium(III) Chloride Catalyzed Efficient Synthesis of Unsymmetrical Diorganyl Selenides via Cleavage of Dibenzyl and Diphenyl Diselenides in the Presence of Zinc.J. Org. Chem.2005,70, 7338-7341.
11.Zhao, X.; Yu, Z.;* Zeng, F.; Chen, J.; Wu, X.; Wu, S.; Xiao, W.-J.;* Zheng, Z. Highly Efficient Route to Diselenides from the Reactions of Imines and Selenium in the Presence of Carbon Monoxide and Water.Adv. Synth. Catal.2005,347, 877-882.